Chemistry is built on a foundation of understanding how elements and compounds interact, and Avogadro’s number plays a crucial role in unlocking these mysteries. By defining relationships between atoms, molecules, and their corresponding masses, Avogadro’s number provides chemists with essential tools for making sense of molecular structures and reactions. To delve into concepts like gram atomic mass and gram molecular mass, we must first clarify some fundamental principles. This comprehensive post will break down each term and provide detailed examples for a better understanding of the underlying concepts.
Table of Contents
Avogadro’s Number and Its Significance
Avogadro’s number, represented as NA, is equal to 6.022 × 10²³ and is one of the most important constants in chemistry. This number defines the quantity of entities, such as atoms, molecules, or ions, present in one mole of a substance. Understanding Avogadro’s number is key to grasping the concepts of molecular mass, atomic mass, and the calculations related to chemical reactions.
For instance, in the case of water (H₂O), one atom of oxygen (O) bonds with two atoms of hydrogen (H) to form a water molecule. Therefore, one mole of oxygen atoms (6.022 × 10²³ O atoms) will combine with two moles of hydrogen atoms (2 × 6.022 × 10²³ H atoms) to form one mole of water molecules. Each of these moles represents a huge quantity of particles, and it’s through Avogadro’s number that we can comprehend the vastness of these figures.
Another important feature of Avogadro’s number is its direct link to molar mass. The mass of one mole of a substance is equal to the molecular weight (measured in atomic mass units, or a.m.u.) of that substance. For example, the mean molecular weight of water is 18.015 a.m.u., which means that one mole of water weighs 18.015 grams. This feature simplifies many chemical calculations, making it easier to predict the quantities of reactants and products involved in chemical reactions.
Atomic Mass: Definition and Examples
Before we explore gram atomic mass, it’s essential to understand the term atomic mass. The atomic mass of an element is the mass of a single atom of that element, typically measured in atomic mass units (a.m.u.), which is often denoted as u. One atomic mass unit is defined as exactly 1/12th the mass of one atom of carbon-12 (C-12). This value is determined by dividing the mass of one mole of C-12 atoms by Avogadro’s Constant.
For example:
- Hydrogen (H) has an atomic mass of 1 a.m.u.
- Carbon (C) has an atomic mass of 12 a.m.u.
- Oxygen (O) has an atomic mass of 16 a.m.u.
These atomic masses represent the average mass of an atom of each element. When calculating the mass of larger compounds or elements, we sum the atomic masses of the component atoms.
Molecular Mass: Summing Atomic Masses
Molecular mass refers to the total mass of a molecule, which is the sum of the masses of all the atoms present in that molecule. The unit for molecular mass is also a.m.u. (atomic mass unit). For example, let’s calculate the molecular mass of ammonia (NH₃):
- The atomic mass of nitrogen (N) is 14 a.m.u.
- The atomic mass of hydrogen (H) is 1 a.m.u.
The molecular formula for ammonia shows one nitrogen atom and three hydrogen atoms, so the molecular mass of NH₃ would be:
$$
14 \, \text{a.m.u. (N)} + (3 \times 1 \, \text{a.m.u. (H)}) = 17 \, \text{a.m.u.}
$$
Thus, the molecular mass of NH₃ is 17 a.m.u.
Molar Mass: From Atomic and Molecular Mass to Grams
Molar mass is a critical concept in chemistry, as it relates to the mass of one mole of a substance. The SI unit of molar mass is kg/mol, but it’s more commonly expressed in g/mol. The molar mass is essentially the molecular mass of a substance expressed in grams.
For example, let’s consider hydrogen gas (H₂):
- The molecular mass of H₂ is 2 a.m.u. (since each hydrogen atom has an atomic mass of 1 a.m.u., and there are two atoms of hydrogen in an H₂ molecule).
- According to the definition, the molar mass of hydrogen gas is 2 g/mol, meaning one mole of hydrogen gas weighs 2 grams.
This principle holds for all substances. For example:
- Oxygen gas (O₂) has a molecular mass of 32 a.m.u., so its molar mass is 32 g/mol.
- Water (H₂O) has a molecular mass of 18.015 a.m.u., so its molar mass is 18.015 g/mol.
The Mole Concept: Understanding Chemical Quantities
The mole is a fundamental unit in chemistry. One mole is defined as the amount of a substance that contains as many entities (atoms, molecules, ions, etc.) as there are atoms in 12 grams of carbon-12. This number, as mentioned earlier, is Avogadro’s Constant (NA = 6.022 × 10²³).
The mole concept allows chemists to express the quantity of chemical substances in terms of moles rather than dealing with incredibly large numbers of individual atoms or molecules. For example, rather than saying a sample contains 6.022 × 10²³ atoms of carbon, we simply say it contains 1 mole of carbon atoms.
The number of entities in 1 mole of a substance is equal to Avogadro’s number, and the mass of 1 mole of a substance (in grams) is equal to its molar mass. For example:
- 1 mole of carbon-12 atoms has a mass of 12 grams.
- 1 mole of water molecules (H₂O) has a mass of 18.015 grams.
- 1 mole of oxygen gas (O₂) has a mass of 32 grams.
Gram Atomic Mass: Definition and Calculation
Gram atomic mass is the atomic mass of an element expressed in grams. It represents the mass of one mole of atoms of an element. To find the gram atomic mass of an element, simply take the element’s atomic mass from the periodic table and express it in grams.
For example:
- The gram atomic mass of helium (He) is 4 grams since the atomic mass of helium is 4 a.m.u.
- The gram atomic mass of sodium (Na) is 22.99 grams, as its atomic mass is 22.99 a.m.u. This means that one mole of sodium atoms weighs 22.99 grams.
The formula to calculate a gram’s atomic mass is:
$$
\text{Mass of the element (in g)} $$ $$ = \frac{\text{Number of gram atoms}}{\text{Atomic mass of the element (in g)}}
$$
Gram Molecular Mass: Definition and Calculation
Gram molecular mass refers to the mass in grams of one mole of a molecular substance. It is the same as molar mass, but the term emphasizes that the substance in question is a molecule rather than a single element.
To calculate the gram molecular mass:
- Write the molecular formula of the substance.
- Look up the atomic mass of each element in the formula.
- Multiply the atomic mass of each element by the number of atoms of that element in the molecule.
- Add the values to get the gram molecular mass.
For example, to calculate the gram molecular mass of oxygen gas (O₂):
- The atomic mass of oxygen is 16 a.m.u.
- There are two atoms of oxygen in an O₂ molecule, so the molecular mass is 2 × 16 = 32 a.m.u.
Thus, the gram molecular mass of oxygen gas is 32 grams.
The formula for calculating the number of gram molecules is:
$$
\text{Number of gram molecules} $$ $$= \frac{\text{Mass of the substance (in g)}}{\text{Molecular mass of the substance (in g)}}
$$
Real-life examples of Gram Atomic and Gram Molecular Mass
Let’s consider the calculation of gram atomic mass and gram molecular mass for several common substances.
- Carbon Dioxide (CO₂): The molecular formula of carbon dioxide is CO₂. To find its gram molecular mass:
- Carbon (C) has an atomic mass of 12 a.m.u.
- Oxygen (O) has an atomic mass of 16 a.m.u.
- The molecular mass of CO₂ is 12 + (2 × 16) = 44 a.m.u.
Therefore, the gram molecular mass of carbon dioxide is 44 grams.
- Sodium Chloride (NaCl): Sodium chloride (table salt) has the molecular formula NaCl.
- The atomic mass of sodium (Na) is 22.99 a.m.u.
- The atomic mass of chlorine (Cl) is 35.45 a.m.u.
- The molecular mass of NaCl is 22.99 + 35.45 = 58.44 a.m.u.
Thus, the gram molecular mass of NaCl is 58.44 grams.
Conclusion
The concepts of gram atomic mass and gram molecular mass provide critical insights into how atoms and molecules are measured in the laboratory. By understanding these terms and using them in calculations, chemists can easily determine the mass of substances in a reaction, predict how much of each reactant is needed, and assess the outcomes of chemical reactions. Whether working with elements or compounds, the ability to convert between atomic mass, molecular mass, and molar mass is a foundational skill for anyone studying or working in the field of chemistry.
Table of Key Concepts in Atomic and Molecular Mass Calculations
The following table summarizes the important concepts related to Avogadro’s number, atomic mass, molecular mass, gram atomic mass, and gram molecular mass. This will help in understanding the connections between these terms and how they are applied in chemical calculations. Each concept is explained in detail, with examples and formulas to provide a deeper insight into their significance in chemistry.
Concept | Definition | Formula or Key Information | Examples |
---|---|---|---|
Avogadro’s Number | The number of atoms, molecules, or entities in one mole of a substance. | 6.022 × 10²³ entities per mole. | One mole of carbon-12 (C-12) contains 6.022 × 10²³ atoms. |
Atomic Mass | The mass of a single atom of an element is typically measured in atomic mass units (a.m.u.). | Measured in a.m.u.. | Hydrogen (H): 1 a.m.u.; Carbon (C): 12 a.m.u.; Oxygen (O): 16 a.m.u. |
Molecular Mass | The sum of the atomic masses of all the atoms in a molecule. | Molecular Mass = Σ (Atomic Masses of atoms in the molecule) | Water (H₂O): 18.015 a.m.u.; Ammonia (NH₃): 17 a.m.u.; Carbon dioxide (CO₂): 44 a.m.u. |
Molar Mass | The mass of one mole of a substance is usually expressed in g/mol or kg/mol. | Molar Mass (g/mol) = Molecular Mass (a.m.u.) expressed in grams | Hydrogen gas (H₂): 2 g/mol; Water (H₂O): 18.015 g/mol; Oxygen gas (O₂): 32 g/mol |
Mole | The amount of a substance containing the same number of entities as there are atoms in 12 g of C-12. | One mole equals 6.022 × 10²³ entities. | 1 mole of carbon atoms weighs 12 grams; 1 mole of water molecules (H₂O) weighs 18.015 grams. |
Gram Atomic Mass | The atomic mass of an element is expressed in grams. | Gram Atomic Mass (g) = Atomic Mass (a.m.u.) expressed in grams | Helium (He): 4 grams; Sodium (Na): 22.99 grams. |
Gram Molecular Mass | The mass in grams of one mole of a molecular substance is same as molar mass. | Gram Molecular Mass (g/mol) = Molecular Mass (a.m.u.) expressed in grams | Oxygen gas (O₂): 32 grams; Carbon dioxide (CO₂): 44 grams; Sodium chloride (NaCl): 58.44 grams. |
Number of Gram Atoms | The number of gram atoms present in a given mass of an element. | Number of Gram Atoms = Mass of the element (in g) / Atomic mass of the element (in g) | For 22.99 g of sodium (Na), the number of gram atoms = 1, as its atomic mass is 22.99 g. |
Number of Gram Molecules | The number of gram molecules in a given mass of a molecular substance. | Number of Gram Molecules = Mass of the substance (in g) / Molecular mass of the substance (in g) | For 32 g of oxygen gas (O₂), the number of gram molecules = 1, as its molecular mass is 32 g. |
Explanation of Key Concepts
- Avogadro’s Number: One of the most important constants in chemistry, Avogadro’s number allows chemists to count individual particles (atoms, molecules) on a scale useful in laboratory settings. It is fundamental in calculating the number of particles in a given amount of material.
- Atomic Mass: This concept refers to the mass of a single atom of an element. For practical purposes, the atomic masses listed in the periodic table are average values, taking into account the different isotopes of each element. Atomic mass is expressed in atomic mass units (a.m.u.), where 1 a.m.u. is defined as 1/12th the mass of one atom of carbon-12 (C-12).
- Molecular Mass: Molecular mass is determined by adding together the atomic masses of all the atoms in a molecule. This allows chemists to determine the overall mass of the molecule and is a key factor in understanding how compounds react.
- Molar Mass: Expressed in g/mol, the molar mass provides the mass of one mole of a substance. It is calculated by converting the molecular mass (expressed in a.m.u.) into grams. This concept simplifies the study of chemical reactions, as it allows for easy comparison between amounts of substances.
- Mole Concept: The mole is a unit that enables chemists to express large quantities of particles in a manageable way. One mole contains 6.022 × 10²³ entities (whether atoms, molecules, ions, or electrons). By using moles, chemists can calculate the amounts of substances involved in reactions more easily.
- Gram Atomic Mass: The gram atomic mass is the atomic mass of an element converted into grams. This mass represents one mole of atoms for that element. For example, the gram atomic mass of carbon (C) is 12 grams, since its atomic mass is 12 a.m.u..
- Gram Molecular Mass: Like gram atomic mass, gram molecular mass converts the molecular mass into grams. This represents the mass of one mole of molecules for the substance. For example, the gram molecular mass of carbon dioxide (CO₂) is 44 grams, and its molecular mass is 44 a.m.u.
- Number of Gram Atoms: This calculation tells us how many gram atoms (or moles of atoms) are present in a given mass of an element. For example, if you have 22.99 grams of sodium (Na), you have a 1-gram atom because the atomic mass of sodium is 22.99 g.
- Number of Gram Molecules: Similar to the number of gram atoms, this concept tells us how many gram molecules (or moles of molecules) are present in a given mass of a molecular substance. For example, 32 grams of oxygen gas (O₂) contain 1 gram molecule, as the molecular mass of oxygen gas is 32 g/mol.
This detailed breakdown provides a foundation for understanding chemical calculations related to atomic mass, molecular mass, and moles, crucial concepts for chemists working with reactions, compounds, and the periodic table.
Related Article
- Dalton’s Atomic Theory: An Interesting Groundbreaking Scientific Concept
- Laws of Chemical Combination: The Foundations of Chemical Reactions
- Understanding Measurement Uncertainty in Chemistry with Perfect Explanation
- Properties of Matter: An In-Depth Exploration
- Understanding Matter: States, Properties, and Beyond
- The Importance of Chemistry in Everyday Life
Frequently Asked Questions (FAQs)
What is Avogadro’s number, and why is it important?
Avogadro’s number, which is 6.022 × 10²³, represents the number of atoms, molecules, or other entities in one mole of a substance. This number is essential in chemistry because it allows scientists to count large quantities of particles in a substance, making it easier to work with microscopic entities on a macroscopic scale. For example, one mole of carbon-12 (C-12) atoms contains 6.022 × 10²³ atoms.
What is the difference between atomic mass and molecular mass?
Atomic mass refers to the mass of a single atom of an element, measured in atomic mass units (a.m.u.), while molecular mass is the sum of the atomic masses of all the atoms in a molecule. For example, the atomic mass of hydrogen (H) is 1 a.m.u., and the molecular mass of water (H₂O) is 18.015 a.m.u. (2 hydrogen atoms and 1 oxygen atom).
How is molar mass related to molecular mass?
Molar mass is the molecular mass expressed in grams per mole (g/mol). While molecular mass is calculated in a.m.u., molar mass converts this into grams, making it easier to use in laboratory calculations. For example, the molecular mass of oxygen gas (O₂) is 32 a.m.u., and its molar mass is 32 g/mol.
What is the significance of one mole in chemistry?
A mole is a unit used to express an amount of a substance. It contains exactly 6.022 × 10²³ particles (atoms, molecules, or ions), which corresponds to Avogadro’s number. This concept is significant because it allows chemists to easily calculate the number of particles in a given mass of a substance. For example, 1 mole of water (H₂O) contains 6.022 × 10²³ molecules.
How do you calculate the number of atoms in a mole of an element?
To calculate the number of atoms in a mole of an element, simply multiply the number of moles by Avogadro’s number (6.022 × 10²³). For example, 1 mole of sodium (Na) contains 6.022 × 10²³ sodium atoms.
What is the difference between gram atomic mass and gram molecular mass?
Gram atomic mass is the atomic mass of an element expressed in grams, representing the mass of one mole of the element. Gram molecular mass is the molecular mass expressed in grams, representing the mass of one mole of a molecular substance. For example, the gram atomic mass of helium (He) is 4 grams, while the gram molecular mass of water (H₂O) is 18.015 grams.
How do you calculate the molecular mass of a compound?
To calculate the molecular mass of a compound, sum the atomic masses of all the atoms in the molecule. For instance, the molecular formula of ammonia (NH₃) consists of one nitrogen atom and three hydrogen atoms:
- Nitrogen (N): 14 a.m.u.
- Hydrogen (H): 1 a.m.u. each
Thus, the molecular mass of NH₃ is 14 + (3 × 1) = 17 a.m.u..
What is the gram atomic mass of carbon?
The gram atomic mass of carbon (C) is 12 grams since the atomic mass of carbon is 12 a.m.u. This means that one mole of carbon atoms weighs exactly 12 grams.
How is the molar mass of a substance used in chemical reactions?
The molar mass is used to determine the mass of a substance involved in a chemical reaction. By converting the number of moles into grams using the molar mass, chemists can calculate how much of each reactant is required or how much product will form. For example, if 2 moles of oxygen gas (O₂) are used in a reaction, their mass would be 2 × 32 g/mol = 64 grams.
What is the molecular mass of water (H₂O)?
The molecular mass of water (H₂O) is 18.015 a.m.u. This is calculated by adding the atomic masses of 2 hydrogen atoms (1 a.m.u. each) and 1 oxygen atom (16 a.m.u.):
- (2 × 1) + 16 = 18 a.m.u.
Why is Avogadro’s number called a constant?
Avogadro’s number is called a constant because it is a fixed, universal value that applies to any element or compound. No matter what substance you are dealing with, 6.022 × 10²³ entities are always present in one mole.
What is the molar mass of carbon dioxide (CO₂)?
The molar mass of carbon dioxide (CO₂) is 44 grams per mole (g/mol). This is derived from the molecular mass:
- Carbon (C): 12 a.m.u.
- Oxygen (O): 16 a.m.u. each (2 oxygen atoms)
Thus, the molecular mass of CO₂ is 12 + (2 × 16) = 44 a.m.u., and the molar mass is 44 g/mol.
How is the number of gram molecules calculated?
The number of gram molecules is calculated using the formula:
Number of gram molecules = Mass of the substance (in g) / Molecular mass of the substance (in g)
For example, if you have 32 grams of oxygen gas (O₂), the number of gram molecules is 32 g / 32 g/mol = 1 gram molecule.
What is the atomic mass of sodium (Na)?
The atomic mass of sodium (Na) is 22.99 a.m.u.. This is the average mass of one sodium atom and is found on the periodic table.
What is the relationship between molar mass and Avogadro’s number?
The Molar mass and Avogadro’s number are related because the molar mass tells you how many grams of a substance are needed to contain 6.022 × 10²³ particles (one mole). For instance, 12 grams of carbon contains 6.022 × 10²³ carbon atoms, and this mass is the molar mass of carbon.
How do you find the number of atoms in 12 grams of carbon?
Since 12 grams of carbon is equivalent to 1 mole, it contains exactly 6.022 × 10²³ carbon atoms, as per Avogadro’s number.
What is the gram molecular mass of ammonia (NH₃)?
The gram molecular mass of ammonia (NH₃) is 17 grams. This is calculated by adding the atomic masses of nitrogen (N) and hydrogen (H):
- Nitrogen (N): 14 a.m.u.
- Hydrogen (H): 1 a.m.u. each (3 hydrogen atoms)
Thus, 14 + (3 × 1) = 17 a.m.u., and the gram molecular mass is 17 grams.
What does the term “mole” signify in chemistry?
The term mole refers to a quantity of 6.022 × 10²³ particles (atoms, molecules, or ions) of a substance. It allows chemists to work with amounts of material that can be measured and used in experiments.
How is the number of gram atoms calculated?
The number of gram atoms is calculated using the formula:
Number of gram atoms = Mass of the element (in g) / Atomic mass of the element (in g)
For example, if you have 22.99 grams of sodium (Na), the number of gram atoms is 1, since its atomic mass is 22.99 g.
What is the mass of one mole of helium (He)?
The mass of one mole of helium (He) is 4 grams since the atomic mass of helium is 4 a.m.u. This means that one mole of helium atoms weighs 4 grams.
What is the relationship between atomic mass units (a.m.u.) and grams?
Atomic mass units (a.m.u.) are used to measure the mass of atoms and molecules on a microscopic scale. One a.m.u. is defined as 1/12th the mass of a carbon-12 (C-12) atom, which is approximately 1.660539 × 10⁻²⁴ grams. This small unit allows chemists to express the mass of atoms without dealing with extremely small decimal values. The relationship between a.m.u. and grams becomes essential when converting molecular mass (in a.m.u.) to molar mass (in grams per mole). For example, the atomic mass of hydrogen (H) is approximately 1 a.m.u., and thus 1 mole of hydrogen weighs about 1 gram.
How does Avogadro’s number help in converting between grams and moles?
Avogadro’s number (6.022 × 10²³) serves as a bridge between the microscopic world of atoms and molecules and the macroscopic world of grams and moles. By using Avogadro’s number, we can convert the mass of a substance (in grams) to the number of moles, and then determine how many atoms or molecules are present in that mass. For example, if we have 12 grams of carbon (C), which corresponds to 1 mole, Avogadro’s number tells us that there are 6.022 × 10²³ carbon atoms in that mass. This helps in balancing chemical reactions and calculating reactants and products on a large scale.
How do you calculate the molar mass of a compound with multiple elements?
To calculate the molar mass of a compound composed of multiple elements, sum the atomic masses of all the atoms in the molecular formula. The molar mass is expressed in grams per mole (g/mol), representing the mass of one mole of that compound. For example, for sulfuric acid (H₂SO₄), the molar mass is calculated as follows:
- Hydrogen (H): 1.008 g/mol (2 atoms)
- Sulfur (S): 32.06 g/mol (1 atom)
- Oxygen (O): 16.00 g/mol (4 atoms)
Thus, the molar mass of H₂SO₄ = (2 × 1.008) + 32.06 + (4 × 16.00) = 98.08 g/mol. This means that one mole of sulfuric acid weighs 98.08 grams.
Why is molar mass an important concept in chemical reactions?
Molar mass is crucial in chemical reactions because it allows chemists to translate the moles of substances into measurable amounts in grams. This is essential for determining the exact proportions of reactants and products in a reaction. For example, in the combustion of methane (CH₄), the balanced chemical equation is:
$$ \text{CH₄} + 2\text{O₂} \rightarrow \text{CO₂} + 2\text{H₂O} $$
To determine how much oxygen gas (O₂) is needed to completely react with 1 mole of methane (CH₄), we use the molar masses: 16.04 g/mol for CH₄ and 32.00 g/mol for O₂. Therefore, 1 mole of CH₄ (16.04 grams) will require 2 moles of O₂ (64 grams). Without knowing molar mass, such precise calculations would be impossible.
How can the mole concept be applied to gases?
The mole concept can be extended to gases using Avogadro’s law, which states that equal volumes of all gases, at the same temperature and pressure, contain the same number of molecules. For example, 1 mole of any gas occupies 22.414 liters at standard temperature and pressure (STP). This volume is known as the molar volume of a gas. By applying the mole concept, we can calculate the volume of gas produced or consumed in a chemical reaction. For instance, 1 mole of oxygen gas (O₂) at STP occupies 22.414 liters, meaning that 6.022 × 10²³ oxygen molecules fit into this volume under standard conditions.
How do you determine the mass of a single atom of an element?
To find the mass of a single atom, divide the atomic mass of the element by Avogadro’s number. For example, the atomic mass of gold (Au) is 197 grams per mole. Since 1 mole of gold contains 6.022 × 10²³ atoms, the mass of a single gold atom is:
$$
\text{Mass of one gold atom}$$ $$ = \frac{197 \, \text{g}}{6.022 × 10²³} ≈ 3.27 × 10^{-22} \, \text{grams}
$$
This calculation shows how small the mass of a single atom is, illustrating why Avogadro’s number is so important for dealing with large numbers of particles.
What is the role of the mole in stoichiometry?
In stoichiometry, the mole plays a key role in determining the proportions of reactants and products in a chemical reaction. Stoichiometric calculations involve converting the amounts of substances (often given in grams) into moles using their molar masses. From there, the balanced chemical equation provides the mole ratios needed to calculate how much of each reactant is required or how much of each product will be formed. For example, in the reaction between hydrogen (H₂) and oxygen (O₂) to form water (H₂O):
$$
2\text{H₂} + \text{O₂} \rightarrow 2\text{H₂O}
$$
If we start with 2 moles of H₂, we know from the balanced equation that 1 mole of O₂ is required, and 2 moles of H₂O will be produced.
How do you calculate the number of molecules in a given mass of a substance?
To calculate the number of molecules in a given mass of a substance, follow these steps:
- Convert the mass of the substance to moles by dividing by the molar mass.
- Multiply the number of moles by Avogadro’s number to get the total number of molecules.
For example, suppose we have 18 grams of water (H₂O). The molar mass of water is 18.015 g/mol, so:
$$
\text{Moles of water} $$ $$ = \frac{18 \, \text{g}}{18.015 \, \text{g/mol}} ≈ 1 \, \text{mole}
$$
Since 1 mole of water contains 6.022 × 10²³ molecules, we have 6.022 × 10²³ water molecules in the 18 grams of water.
What is the difference between empirical formula mass and molecular formula mass?
The empirical formula mass is the sum of the atomic masses in the simplest ratio of atoms in a compound, whereas the molecular formula mass is the sum of the atomic masses in the actual number of atoms present in a molecule. For example, the empirical formula of glucose is CH₂O, representing the simplest ratio of carbon, hydrogen, and oxygen atoms, with a mass of 30 a.m.u.. The molecular formula of glucose, however, is C₆H₁₂O₆, with a mass of 180 a.m.u.. The empirical formula gives a basic ratio, while the molecular formula provides the actual number of atoms in the molecule.
Why is Avogadro’s constant the same for all substances?
Avogadro’s constant represents a fundamental number that applies universally to all substances, regardless of their chemical identity. It is based on the concept that a mole of any substance contains the same number of particles (atoms, molecules, ions). Whether dealing with carbon atoms, water molecules, or sodium ions, one mole always contains 6.022 × 10²³ entities. This constancy makes Avogadro’s number an essential tool for comparing and calculating the amounts of different substances in chemical reactions.